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Sludgy 07-03-2006 05:57 AM

A better fuel than ethanol
 
Butanol, made from corn.

Environmental Energy Main Page

zpiloto 07-03-2006 02:12 PM

Quote:

Originally Posted by Sludgy
Butanol, made from corn.

Environmental Energy Main Page

Why are they pushing for ethanol and not Butanol:confused:. Is it environmentally unfriendly?

GasSavers_Ryland 07-03-2006 08:42 PM

wow, that is a great sales pitch from a compeny that holds a patent to produce "our only hope"

All the other costs that they quote are only estamations in a best case, it seems they don't have any real numbers, the closest they have is that if you compair their cost to produce butanol from corn, compaired to producing it from oil is a savings up to $.15 a gallon, "Our preliminary cost estimates suggest that we can produce butanol from corn for about $1.20 per gallon,"

"
As a further point of reference, butanol produced from petroleum costs about $1.35 per gallon to manufacture."

"
Butanol currently sells for about $3.70 per gallon in bulk (barge) and $6.80 in 55 gallon drums."

Some how I don't think that 15 cents per gallon savings is going to drop the cost of a barge of fuel down below $3.00 if it's currently at $3.70 a gallon, and that I assume is if you pick it up at the dock in your very own tanker trucks, tack on road tax, and paying Abu at the Quicki Mart, and the cost of having people drive off without paying, and sudenly this is looking like a pretty exspensive fuel.
maybe my negative tone is from living on a farm that 100 years ago had awsome soil that could grow anything, and now it's in a program to protect it from soil erosion because of over farming, altho I'm sure we can find alot of other land to over farm, and that altho corn is one of the worst crops for soil erosion, we will find a solution befor it's compleatly to late.

SVOboy 07-03-2006 08:46 PM

But they also say it's cheaper to produce than ethanol, and look at brazil selling ethanol for less than gas, :(

GasSavers_Ryland 07-03-2006 09:08 PM

why is it not for sale? did you read this part?

"Butanol is used primarily as an industrial solvent. The worldwide market is about 350 million gallons per year with the U.S. market accounting for about 220 million gallons per year. Butanol currently sells for about $3.70 per gallon in bulk (barge) and $6.80 in 55 gallon drums."

If I wanted to buy a barge of gasoline do you think I would be paying $3.00 a gallon? I don't think so, subtract transportation cost, fuel taxes, the cut that the gas station takes, and all the other small costs that ad up, and then look at any other fuel and do the same thing to it, and the cost of a barge of fuel gets closer to what you might pay if you wanted to buy it 55 gallons at a time.
oh, right, and as the price of oil goes up, the price of corn goes up, and the cost to prosses that corn goes up, it's kind of like running a gas generator to charge your electric car to beat the cost of gasoline... are we bad at math?

Sludgy 07-04-2006 07:33 AM

Not sure about the economics of either ethanol or butanol. Both may cost more than oil. But they're both renewable, and if the US wanted to tell the imam's to drink their oil, we could do it.

Butanol's 94 octane rating is "racing gas". Butanol has almost as much energy as gasoline. It also has a much lower evaporation rate than gas so evaporative emissions are lower.

Seems like there are lots of reasons to use it regardless of the cost.

Matt Timion 07-04-2006 07:40 AM

Quote:

Originally Posted by SVOboy
But they also say it's cheaper to produce than ethanol, and look at brazil selling ethanol for less than gas, :(

Comparing the USA to Brazil is pointless. Brazil has an abundant supply of ethanol due to a massive crop of sugar cane. The USA has corn, which is more difficult to turn into ethanol.

Unless you can suddenly turn the USA into a tropical climate and give us a huge crop of sugar cane, comparing us to Brazil is like comparing apples to oranges.

SVOboy 07-04-2006 09:18 AM

I think you miss the point that it's cheaper than ethanol, which is being pushed heavily here...

Matt Timion 07-04-2006 09:21 AM

Quote:

Originally Posted by SVOboy
I think you miss the point that it's cheaper than ethanol, which is being pushed heavily here...

Okay, it's cheaper than ethanol, but what does the price of ethanol in Brazil have to do with it?

Ethanol costs a lot more to produce here than in Brazil.

SVOboy 07-04-2006 09:27 AM

Indeed, but if we could produce something more cheaply...

cheapybob 07-04-2006 11:05 AM

One of the reasons ethanol from sugar cane is so much cheaper is because the crop only needs to be planted every 5 yrs, not every yr like corn. That means a lot less tractor time and fuel used per acre per yr.

Another reason is because labor is so much cheaper in Brazil.

I wonder if there is some other thing that would grow real well in our climate from which we could produce fuel more efficiently than corn? Maybe a fast growing softwood?

Matt Timion 07-04-2006 12:33 PM

Quote:

Originally Posted by cheapybob
One of the reasons ethanol from sugar cane is so much cheaper is because the crop only needs to be planted every 5 yrs, not every yr like corn. That means a lot less tractor time and fuel used per acre per yr.

Another reason is because labor is so much cheaper in Brazil.

I wonder if there is some other thing that would grow real well in our climate from which we could produce fuel more efficiently than corn? Maybe a fast growing softwood?

Excellent points. I'm also certain that Brazil has a longer crop season than America. In America you can only grow crops for a few months per year. In certain parts of Brazil I'm certain it's year-long.

The Toecutter 07-04-2006 03:48 PM

Quote:

I wonder if there is some other thing that would grow real well in our climate from which we could produce fuel more efficiently than corn?
Industrial Hemp.

But this overbloated government, and the oil, pharmaceutical, petrochemical, wood paper, steel, and defense industries that finance it just will not allow it. Even though you cannot get stoned off of industrial hemp, our government still prosecutes people for growing it without a permit the same as if they were marijuana farmers. The catch is, the government has never granted anyone a permit to grow it and refuses to.

rh77 07-04-2006 05:34 PM

They're really pusing this Ethanol
 
There was an Ethanol "awareness" conference at one the hotels in town -- I sort of stumbled across it last weekend. They converted a Lambo, Maserati, 911, Z06, F430, and an Indy Car to Ethanol, and had it on display. It was quite a display, but I didn't have the heart to tell them that each combustion had less potential energy than other, less-polluting alternatives. I'm still not sold on it...

RH77

Sludgy 07-18-2006 07:35 AM

Quote:

Originally Posted by The Toecutter
Industrial Hemp.

But this overbloated government, and the oil, pharmaceutical, petrochemical, wood paper, steel, and defense industries that finance it just will not allow it. Even though you cannot get stoned off of industrial hemp, our government still prosecutes people for growing it without a permit the same as if they were marijuana farmers. The catch is, the government has never granted anyone a permit to grow it and refuses to.

AH, hemp.... brings me back to my salad days.

Hemp may be a useful fiber, but it's lousy for making liquid fuels. There is a reason that sugar cane and corn are used to make ethanol. Starches and sugars are easy to ferment. On the other hand, hemp, like any other cellulosic material, needs to be broken down into sugars before fermentation. Cellulose is very difficult to break down.

In any case, if cellulosic plants are to be used, the best ones would need little or no chemical nitrogen fertilizer. Some kind of self-seeding nitrogen fixing legume (alfalfa or clover?) would be better than hemp, which needs nitrogen fertilizers (made from natural gas) and which must be planted every year.

Soybeans might be a good choice for alcohol fuel too. Although beans need to be planted every year, you could make biodiesel from soybean oil, and ferment the remaining soybean meal to alcohols.

JanGeo 07-18-2006 09:32 AM

Talking to a couple from Florida yesterday about this - apparently they can grow sugar cane there and they do. Advantage of corn is the waste is usable - not sure about the sugar cane stalks.

The Toecutter 07-18-2006 10:37 AM

Hemp isn't useful for ethanol.

Biodiesel is where it is exceptionally useful, arguably moreso than soy or other plants.

It needs no fertilizer or pesticide inputs. It can grow in a wide variety of climates, up from the equatorial regions and into Canada. As opposed to helping erode soil like corn often does, it actually replenishes it and helps prevent erosion.

The hempseeds are extracted and crushed to obtain the oil. From that, biodiesel can be made.

Energy Return of Energy Invested is on par with sugarcane ethanol.

Corn ethanol pretty much breaks even with the manmade energy inputs, sometimes takes more energy. Sugarcane ethanol has an EROEI over 5, which is why Brazil is making such wide use of it, it works(although at the expense of rainforest. :().

Hemp produces about 305 kg of oil per hectare. This is about 70 kg less than soybeans, but the overall efficiency is higher than and impact on the environment much less than soy.

It can be grown in arid climates as well, so we won't have to cut down all of our forests to grow it.

***edit***

Please read the following article for a brief summary of hemp as a biofuel:

https://mit.edu/thistle/www/v13/2/enviro.html

Sludgy 07-18-2006 11:44 AM

Quote:

Originally Posted by The Toecutter
Hemp isn't useful for ethanol.

Biodiesel is where it is exceptionally useful, arguably moreso than soy or other plants.

It needs no fertilizer or pesticide inputs. It can grow in a wide variety of climates, up from the equatorial regions and into Canada. As opposed to helping erode soil like corn often does, it actually replenishes it and helps prevent erosion.

The hempseeds are extracted and crushed to obtain the oil. From that, biodiesel can be made.

Energy Return of Energy Invested is on par with sugarcane ethanol.

Corn ethanol pretty much breaks even with the manmade energy inputs, sometimes takes more energy. Sugarcane ethanol has an EROEI over 5, which is why Brazil is making such wide use of it, it works(although at the expense of rainforest. :().

Hemp produces about 305 kg of oil per hectare. This is about 70 kg less than soybeans, but the overall efficiency is higher than and impact on the environment much less than soy.

It can be grown in arid climates as well, so we won't have to cut down all of our forests to grow it.

***edit***

Please read the following article for a brief summary of hemp as a biofuel:

https://mit.edu/thistle/www/v13/2/enviro.html

Hmmm, I find one sentence in that article highly questionable:

"Hemp does not deplete the nutrients in soil, and even purifies the earth by absorbing heavy-metal contaminants."

This sentence is bunk on two counts:

First, all plants remove potassium and phosphorous from soil. If hemp is harvested and processed off site, those essential plant nutrients eventually will be depleted from the soil. And since hemp is not a nitrogen-fixing legume, the same holds true for soil nitrogen. Remember the Law of Conservation of Matter? "Matter can neither be created nor destroyed".

Second, if hemp absorbs heavy metal contaminants, then the hemp itself will contain it. Processing it for fuel or burning it will either disperse it into the air will create an emission or waste disposal issue. I suppose that one could put those heavy metal back into the fields from which they came, but where is the benefit claimed?

Such inconvenient truths detract from the article's credibility. Have you actually read the references to see whether the other assertions in the article are supported by research? Maybe the authors smoke too much.

The Toecutter 07-18-2006 08:43 PM

Quote:

First, all plants remove potassium and phosphorous from soil. If hemp is harvested and processed off site, those essential plant nutrients eventually will be depleted from the soil. And since hemp is not a nitrogen-fixing legume, the same holds true for soil nitrogen.
The amount of nutrients it requires is so low relative to that of other plants, that it is perfectly feasible to plant hemp on the same plot of land for nearly 15 years in a row, without any crop rotation needed and without soil erosion resulting.

Historically, farmers used to use hemp to prepare their soil for more demanding crops, like wheat or corn.

Most of this is due to the roots remaining in the soil and containing much of the nutrients, leaves falling off of the plant, mostly returning the nutrients taken back to the soil, before it is even harvested.

Hemp will need roughly 150-170 kg/hectare of potassium, but the vast majority of it, ~70-95% depending on many factors, will be returned to the soil before the seeds and fibers can even be harvested. Even more nutrients can be reclaimed by returning unused trimmings to the soil.

Quote:

Second, if hemp absorbs heavy metal contaminants, then the hemp itself will contain it. Processing it for fuel or burning it will either disperse it into the air will create an emission or waste disposal issue. I suppose that one could put those heavy metal back into the fields from which they came, but where is the benefit claimed?
The benefit comes from being able to use hemp plants as a means to absorb heavy metals, and soley for that use. They don't have to have multiple purposes with the same crop. It's easier to collect such toxins within plant matter itself, than to try to manually clean the soil of such heavy metals.

Quote:

Have you actually read the references to see whether the other assertions in the article are supported by research?
I've read some of them, but haven't had the time to scour them all. Not yet anyway. I have read studies not mentioned in this article that do support its thesis.

Quote:

Maybe the authors smoke too much.
Not that there's anything wrong with that. ;)

ZugyNA 07-19-2006 04:49 AM

https://www.fromthewilderness.com/fre...questions.html

"Ethanol is another case in point. Some research has shown a negative EROEI for ethanol. Newer research from Oregon shows a slightly positive return. Ethanol is, at best, a slightly beneficial temporary alternative - not a substitute."

Ethanol is a subsidy for farmers and Cargill?

https://www.eroei.com/eval/net_energy_list.html

JanGeo 04-23-2007 03:09 AM

https://tech.groups.yahoo.com/group/ETList/message/7077

Great ETList article on betanol including molecule and comparison to methanol, ethanol and gasoline.

Bill in Houston 04-23-2007 06:12 AM

The flash point of butanol is wayyyy to high for it to be a decent replacement for gasoline...
https://en.wikipedia.org/wiki/Butanol

But I am glad that people are thinking...

repete86 04-23-2007 06:29 AM

Quote:

Originally Posted by JanGeo (Post 20068)
Talking to a couple from Florida yesterday about this - apparently they can grow sugar cane there and they do. Advantage of corn is the waste is usable - not sure about the sugar cane stalks.

We grow a ****load of sugar down here, and it's killing the everglades. Sugar refineries are bad things.


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